Question 1 of 78Alkalies, Acids, Industrial Gases and Solvents
In the electrolysis of brine, chlorine is liberated at the
Aboth electrodes
Banode
Ccathode
Ddiaphragm
Answer is hidden
Question 2 of 78Alkalies, Acids, Industrial Gases and Solvents
Which chlor-alkali cell gives the lowest overall energy consumption and is the standard for new plants?
ACastner-Kellner cell
BMercury cell
CMembrane cell
DDiaphragm cell
Answer is hidden
Question 3 of 78Alkalies, Acids, Industrial Gases and Solvents
In the Solvay process for soda ash, the substance recovered and recycled is
Aammonia
Bsodium bicarbonate
Ccalcium chloride
Dcarbon dioxide only
Answer is hidden
Question 4 of 78Alkalies, Acids, Industrial Gases and Solvents
The Solvay process cannot be used economically to manufacture potassium carbonate because
Aammonia does not dissolve in potassium solutions
Bpotassium bicarbonate is too soluble to precipitate from the solution
Cthe reaction is endothermic
Dpotassium chloride is unavailable
Answer is hidden
Question 5 of 78Alkalies, Acids, Industrial Gases and Solvents
The catalyst used in the contact process for the manufacture of sulphuric acid is
Aplatinum gauze
Bnickel on alumina
Cpromoted iron
Dvanadium pentoxide
Answer is hidden
Question 6 of 78Alkalies, Acids, Industrial Gases and Solvents
In the contact process, sulphur trioxide is absorbed in 98 per cent sulphuric acid rather than in water because
Aabsorption in water produces a fine acid mist that is difficult to capture
Bwater would decompose the sulphur trioxide
Cthe reaction with water is endothermic
Dsulphur trioxide is insoluble in water
Answer is hidden
Question 7 of 78Alkalies, Acids, Industrial Gases and Solvents
In the Ostwald process for nitric acid, ammonia is oxidised over
Aplatinum-rhodium gauze at about 900 ยฐC
Bpromoted iron at about 500 ยฐC
Ccopper-zinc oxide at about 250 ยฐC
Dvanadium pentoxide at about 450 ยฐC
Answer is hidden
Question 8 of 78Alkalies, Acids, Industrial Gases and Solvents
Nitric acid cannot be concentrated beyond about 68 per cent by simple distillation because
Ait becomes immiscible with water
Bit decomposes above that concentration
Cit forms a minimum-boiling azeotrope
Dit forms a maximum-boiling azeotrope with water at that composition
Answer is hidden
Question 9 of 78Alkalies, Acids, Industrial Gases and Solvents
In the cryogenic separation of air, the component that is removed first as a vapour from the top of the column is
Anitrogen, because it is the more volatile
Bargon, because it is present in trace amounts
Ccarbon dioxide
Doxygen, because it is the more volatile
Answer is hidden
Question 10 of 78Alkalies, Acids, Industrial Gases and Solvents
Acetylene for industrial use is stored dissolved in acetone on a porous filler because
Aacetylene is unstable and can decompose explosively if compressed alone
Bacetylene reacts with steel cylinders
Cacetone increases the calorific value
Dacetylene is a liquid at room temperature
Answer is hidden
Question 11 of 78Alkalies, Acids, Industrial Gases and Solvents
Water gas is manufactured by passing steam over incandescent coke; the process is operated in a blow-and-run cycle because
Athe coke must be replaced after each run
Bthe reaction produces too much heat to sustain
Cthe steam reaction is endothermic and cools the bed, which must be reheated by an air blow
Dthe steam supply is intermittent
Answer is hidden
Question 12 of 78Alkalies, Acids, Industrial Gases and Solvents
In the Haber-Bosch process, the catalyst used is
Aplatinum-rhodium
Bpromoted iron
Ccopper-zinc oxide
Dvanadium pentoxide
Answer is hidden
Question 13 of 78Alkalies, Acids, Industrial Gases and Solvents
The cumene process is industrially important because it produces
Aphenol and acetone together in fixed proportion
Bonly acetone
Cbenzene and propylene
Donly phenol
Answer is hidden
Question 14 of 78Cement, Refractories, Glass and Surface Coatings
Gypsum is added to Portland cement clinker during grinding in order to
Aimpart a white colour
Baccelerate the setting of the cement
Cincrease the ultimate strength
Dretard the setting time by controlling the hydration of tricalcium aluminate
Answer is hidden
Question 15 of 78Cement, Refractories, Glass and Surface Coatings
The compound in Portland cement chiefly responsible for early strength development is
Atricalcium silicate (CโS)
Bdicalcium silicate (CโS)
Ctetracalcium aluminoferrite (CโAF)
Dgypsum
Answer is hidden
Question 16 of 78Cement, Refractories, Glass and Surface Coatings
For mass concrete work such as a large dam, the preferred cement is one with
Athe finest possible grinding
Ba high gypsum content
Ca high CโS and low CโA content, giving a low heat of hydration
Da high CโS and high CโA content
Answer is hidden
Question 17 of 78Cement, Refractories, Glass and Surface Coatings
Portland cement hardens by
Aevaporation of the mixing water
Bchemical reaction with water, so it can set under water
Ccrystallisation on cooling
Dabsorption of carbon dioxide from the air
Answer is hidden
Question 18 of 78Cement, Refractories, Glass and Surface Coatings
Magnesite and dolomite refractories are classified as
Abasic refractories
Bneutral refractories
Cacidic refractories
Dinsulating refractories
Answer is hidden
Question 19 of 78Cement, Refractories, Glass and Surface Coatings
A refractory of high porosity generally has
Agood slag resistance and high strength
Bgood insulating value and thermal shock resistance but poor slag resistance and strength
Chigh thermal conductivity
Dthe highest possible refractoriness under load
Answer is hidden
Question 20 of 78Cement, Refractories, Glass and Surface Coatings
In glass manufacture, limestone is added principally to
Aimpart colour to the glass
Blower the melting point of the batch
Cact as a network former
Dact as a stabiliser and make the glass chemically durable and insoluble
Answer is hidden
Question 21 of 78Cement, Refractories, Glass and Surface Coatings
Borosilicate glass is preferred for laboratory glassware because it has
Aa very high refractive index
Ba low coefficient of thermal expansion and therefore high thermal shock resistance
Cthe ability to be cut after tempering
Da lower melting point than soda-lime glass
Answer is hidden
Question 22 of 78Cement, Refractories, Glass and Surface Coatings
The annealing of glass in a lehr is carried out in order to
Arelieve internal stresses developed during forming
Bcolour the glass
Cremove bubbles from the melt
Dincrease the refractive index
Answer is hidden
Question 23 of 78Cement, Refractories, Glass and Surface Coatings
In the float process, molten glass is floated on a bath of
Awater
Bmolten lead
Cmolten tin
Dmolten glass of a different composition
Answer is hidden
Question 24 of 78Cement, Refractories, Glass and Surface Coatings
In a paint formulation, the component that forms the continuous film and determines adhesion and durability is the
Abinder
Bpigment
Cdrier
Dsolvent
Answer is hidden
Question 25 of 78Cement, Refractories, Glass and Surface Coatings
Titanium dioxide is the most widely used white pigment because of its
Aability to act as a solvent
Blow cost compared with all alternatives
Ccatalytic action in drying
Dvery high refractive index, which gives excellent opacity
Answer is hidden
Question 26 of 78Cement, Refractories, Glass and Surface Coatings
A lacquer differs from a varnish and an enamel chiefly in that it
Acontains no resin
Bdries by oxidation with atmospheric oxygen
Cdries purely by evaporation of the solvent, with no chemical change
Dcontains no solvent at all
Answer is hidden
Question 27 of 78Fertilizer Industries
In the fertilizer grade notation, the second and third numbers represent the percentages of
Aelemental P and K
BPโOโ
and KโO
Cphosphate rock and potash ore
Dphosphoric acid and potassium hydroxide
Answer is hidden
Question 28 of 78Fertilizer Industries
The principal reason phosphate rock must be chemically processed before use as a fertilizer is that
Ait is too fine to spread
Bit is chemically unstable
Cit is insoluble and therefore unavailable to plants
Dit contains too much nitrogen
Answer is hidden
Question 29 of 78Fertilizer Industries
In the wet process for phosphoric acid, the major solid by-product is
Aphosphogypsum, calcium sulphate
Bammonium chloride
Csodium sulphate
Dcalcium chloride
Answer is hidden
Question 30 of 78Fertilizer Industries
Triple superphosphate has a much higher PโOโ
content than single superphosphate because
Ait is made with nitric acid
Bit uses a richer grade of phosphate rock
Cit contains added ammonia
Dit is made with phosphoric acid, so no diluting calcium sulphate is formed
Answer is hidden
Question 31 of 78Fertilizer Industries
Diammonium phosphate (DAP) is produced by reacting phosphoric acid with
Apotassium chloride
Bone mole of ammonia per mole of acid
Csulphuric acid
Dtwo moles of ammonia per mole of acid
Answer is hidden
Question 32 of 78Fertilizer Industries
Urea is manufactured from ammonia and carbon dioxide through the intermediate
Aammonium carbonate
Bammonium carbamate
Cammonium nitrate
Dbiuret
Answer is hidden
Question 33 of 78Fertilizer Industries
Urea is the most important solid nitrogenous fertilizer because it has
Ano tendency to absorb moisture
Bthe lowest cost of manufacture of any fertilizer
Can alkaline effect on the soil
Dthe highest nitrogen content of any solid fertilizer, about 46 per cent
Answer is hidden
Question 34 of 78Fertilizer Industries
Biuret in urea fertilizer is undesirable because it is
Atoxic to plants, so its content must be kept below about 1 per cent
Bstrongly hygroscopic
Cresponsible for the fertilizer's colour
Dexplosive on storage
Answer is hidden
Question 35 of 78Fertilizer Industries
Ammonium nitrate requires careful regulation in storage and transport because it
Ais highly corrosive to all metals
Bis a strong oxidiser and presents an explosion hazard
Cis radioactive
Ddecomposes to release ammonia at room temperature
Answer is hidden
Question 36 of 78Fertilizer Industries
Ammonium sulphate fertilizer has the disadvantage that it
Aacidifies the soil on repeated use
Bhas the highest nitrogen content of all fertilizers
Ccannot be applied to alkaline soils
Dcontains no sulphur
Answer is hidden
Question 37 of 78Fertilizer Industries
Potassium sulphate is preferred to potassium chloride for crops such as tobacco and grapes because it
Ahas a higher KโO content
Balso supplies nitrogen
Cis cheaper to manufacture
Dsupplies no chloride, to which these crops are sensitive
Answer is hidden
Question 38 of 78Fertilizer Industries
The Mannheim process is used for the manufacture of
Apotassium sulphate from potassium chloride and sulphuric acid
Bpotassium chloride from sylvinite
Cammonium sulphate from ammonia
Dphosphoric acid from phosphate rock
Answer is hidden
Question 39 of 78Fertilizer Industries
Potassium chloride is separated from sodium chloride in sylvinite ore mainly by flotation
Adistillation
Belectrolysis of the molten ore
Cmagnetic separation
Dfractional crystallisation exploiting the different temperature dependence of their solubilities, or by froth
Answer is hidden
Question 40 of 78Natural Product and Consumer Product Industries
The principal purpose of chemical pulping of wood is to
Adissolve the cellulose
Bbleach the wood white
Cremove all the water from the wood
Ddissolve and remove the lignin so that the cellulose fibres are freed
Answer is hidden
Question 41 of 78Natural Product and Consumer Product Industries
In the kraft pulping process, the active chemicals in the white liquor are
Asodium hydroxide and sodium sulphide
Bsodium hydroxide alone
Ccalcium bisulphite and sulphurous acid
Dchlorine dioxide and oxygen
Answer is hidden
Question 42 of 78Natural Product and Consumer Product Industries
In the kraft recovery cycle, green liquor is converted back to white liquor by
Acausticising with lime to convert sodium carbonate to sodium hydroxide
Bevaporating it in multiple effects
Cadding fresh sulphuric acid
Dburning it in the recovery furnace
Answer is hidden
Question 43 of 78Natural Product and Consumer Product Industries
In a cane sugar mill, bagasse is used principally as
Aan animal feed only
Bfuel to raise steam, making the mill largely energy self-sufficient
Ca clarifying agent for the juice
Da source of additional sucrose
Answer is hidden
Question 44 of 78Natural Product and Consumer Product Industries
Rectified spirit obtained by ordinary distillation of fermented liquor contains about 95 per cent ethanol because
Aethanol and water form a minimum-boiling azeotrope at that composition
Bethanol decomposes above that concentration
Cwater is insoluble in ethanol above 95 per cent
Dthe fermentation cannot proceed beyond that concentration
Answer is hidden
Question 45 of 78Natural Product and Consumer Product Industries
Citric acid is manufactured commercially by fermentation using
ALactobacillus
BSaccharomyces cerevisiae
CEscherichia coli
DAspergillus niger
Answer is hidden
Question 46 of 78Natural Product and Consumer Product Industries
In the hydrogenation of vegetable oils, the iodine value of the product
Aincreases, because new double bonds are formed
Bbecomes zero immediately
Cdecreases, because double bonds are saturated
Dremains unchanged
Answer is hidden
Question 47 of 78Natural Product and Consumer Product Industries
The valuable by-product recovered during the manufacture of soap by saponification is
Acaustic soda
Bglycerine
Csodium chloride
Dfatty alcohol
Answer is hidden
Question 48 of 78Natural Product and Consumer Product Industries
Synthetic detergents are superior to soap in hard water because they
Acontain no surfactant
Bdo not form insoluble precipitates with calcium and magnesium ions
Chave a much higher pH
Ddissolve the hardness salts completely
Answer is hidden
Question 49 of 78Natural Product and Consumer Product Industries
Branched-chain alkylbenzene sulphonate detergents were replaced by the linear form because the branched compounds
Aresist biodegradation and caused persistent foaming in rivers
Bwere too expensive to manufacture
Cwere corrosive to washing machines
Ddid not clean effectively
Answer is hidden
Question 50 of 78Natural Product and Consumer Product Industries
Nylon 6,6 is manufactured by the condensation polymerisation of
Ahexamethylene diamine and adipic acid
Bethylene glycol and terephthalic acid
Cacrylonitrile
Dcaprolactam alone
Answer is hidden
Question 51 of 78Natural Product and Consumer Product Industries
Viscose rayon is correctly described as
Aa condensation polyester
Ba fully synthetic polyamide
Ca regenerated cellulose fibre
Da natural protein fibre
Answer is hidden
Question 52 of 78Natural Product and Consumer Product Industries
Vat dyes such as indigo are applied to cotton by
Adissolving them directly in hot water
Breducing them to a soluble leuco form, applying, and re-oxidising in the fibre
Cdispersing them with a surfactant at high temperature
Dforming a covalent bond with the cellulose
Answer is hidden
Question 53 of 78Petroleum Refining, Petrochemicals and Polymers
Vacuum distillation is used for the atmospheric residue because
Areducing the pressure lowers the boiling temperature and prevents thermal cracking
Batmospheric distillation cannot handle liquids
Cthe residue must be pressurised to separate
Dit increases the relative volatility of all components
Answer is hidden
Question 54 of 78Petroleum Refining, Petrochemicals and Polymers
Catalytic reforming of naphtha is carried out principally to
Acombine small olefins into larger molecules
Bremove sulphur from the feed
Cbreak large molecules into smaller ones
Draise the octane number by converting paraffins and naphthenes to aromatics
Answer is hidden
Question 55 of 78Petroleum Refining, Petrochemicals and Polymers
The catalyst used in modern catalytic reforming is
Apromoted iron
Bplatinum-rhenium on chlorided alumina
Ca zeolite
Dcobalt-molybdenum on alumina
Answer is hidden
Question 56 of 78Petroleum Refining, Petrochemicals and Polymers
In a fluid catalytic cracking unit, the heat required for the endothermic cracking reaction is supplied by
Aan external fired heater on the reactor
Bthe exothermic cracking reactions themselves
Cburning the coke deposited on the catalyst in the regenerator
Delectrical heating of the catalyst
Answer is hidden
Question 57 of 78Petroleum Refining, Petrochemicals and Polymers
Compared with thermal cracking, catalytic cracking produces
Aa higher yield of gasoline with a higher octane number
Bno gasoline at all
Cmore gas and more coke
Da product richer in straight-chain paraffins
Answer is hidden
Question 58 of 78Petroleum Refining, Petrochemicals and Polymers
In the octane number scale, the reference compound assigned a value of 100 is
An-heptane
Biso-octane
Cbenzene
Dn-octane
Answer is hidden
Question 59 of 78Petroleum Refining, Petrochemicals and Polymers
A hydrocarbon with a high octane number will generally have
Aa high cetane number
Bno cetane number at all
Ca low cetane number
Da cetane number equal to its octane number
Answer is hidden
Question 60 of 78Petroleum Refining, Petrochemicals and Polymers
Ethylene and propylene are produced industrially mainly by
Acatalytic reforming of naphtha
Bfractional distillation of crude oil
Csteam cracking of ethane, naphtha or gas oil at 800-900 ยฐC
Dhydrogenation of acetylene
Answer is hidden
Question 61 of 78Petroleum Refining, Petrochemicals and Polymers
The feedstock that gives the highest proportion of ethylene relative to other products in a steam cracker is
Anaphtha
Bheavy gas oil
Cvacuum residue
Dethane
Answer is hidden
Question 62 of 78Petroleum Refining, Petrochemicals and Polymers
Which of the following is a condensation polymer?
APolyvinyl chloride
BPolystyrene
CNylon 6,6
DPolyethylene
Answer is hidden
Question 63 of 78Petroleum Refining, Petrochemicals and Polymers
A thermosetting plastic differs from a thermoplastic in that it
Ais cross-linked into a three-dimensional network and cannot be softened and remoulded
Balways has a lower melting point
Csoftens on heating and can be remoulded repeatedly
Dcontains no carbon
Answer is hidden
Question 64 of 78Petroleum Refining, Petrochemicals and Polymers
High-density polyethylene differs from low-density polyethylene chiefly in that HDPE has
Amore branching and hence greater flexibility
Blinear chains with little branching, giving higher density and rigidity
Ca cross-linked thermosetting structure
Da different monomer
Answer is hidden
Question 65 of 78Petroleum Refining, Petrochemicals and Polymers
Among the formaldehyde resins, the one offering the best hardness, water resistance and surface quality is
Aall three are identical in performance
Burea-formaldehyde
Cphenol-formaldehyde
Dmelamine-formaldehyde
Answer is hidden
Question 66 of 78Nanotechnology
The nanoscale is generally defined as the size range
A1 to 100 nanometres
B1 to 100 micrometres
C1 to 100 millimetres
D100 to 1000 nanometres
Answer is hidden
Question 67 of 78Nanotechnology
The principal reason nanoparticles show greatly enhanced catalytic activity compared with the bulk material is
Atheir lower purity
Btheir very high surface-area-to-volume ratio, which places many more atoms at the surface
Ctheir larger particle mass
Dtheir higher density
Answer is hidden
Question 68 of 78Nanotechnology
Quantum dots emit light of different colours depending on
Athe temperature alone
Bthe shape of the container
Ctheir particle size
Dtheir chemical composition only
Answer is hidden
Question 69 of 78Nanotechnology
A carbon nanotube is classified as a
Athree-dimensional nanomaterial
Bzero-dimensional nanomaterial
Cone-dimensional nanomaterial
Dtwo-dimensional nanomaterial
Answer is hidden
Question 70 of 78Nanotechnology
Graphene is best described as
Aa closed cage of sixty carbon atoms
Ba rolled cylinder of carbon atoms
Ca single atomic layer of carbon atoms in a hexagonal lattice
Dan amorphous form of carbon
Answer is hidden
Question 71 of 78Nanotechnology
Synthesis of nanomaterials by ball milling of a bulk material is an example of
Aa top-down approach
Bchemical vapour deposition
Ca bottom-up approach
Dself-assembly
Answer is hidden
Question 72 of 78Nanotechnology
The melting point of a metallic nanoparticle compared with that of the bulk metal is
Asignificantly lower
Bexactly the same
Csignificantly higher
Dindependent of particle size
Answer is hidden
Question 73 of 78Nanotechnology
Titanium dioxide nanoparticles are used in self-cleaning glass because they
Aabsorb water into the glass
Bphotocatalytically decompose organic dirt under ultraviolet light and make the surface hydrophilic
Creflect all visible light
Dform a hard scratch-resistant layer only
Answer is hidden
Question 74 of 78Nanotechnology
Zinc oxide and titanium dioxide nanoparticles are preferred to their bulk forms in sunscreens because they
Ablock ultraviolet radiation while appearing transparent rather than white on the skin
Babsorb more visible light
Cpenetrate deep into the bloodstream
Dchemically react with ultraviolet light to produce vitamin D
Answer is hidden
Question 75 of 78Nanotechnology
The main advantage of nanoparticle-based targeted drug delivery is that it
Aincreases the toxicity of the drug to healthy tissue
Beliminates the need for any drug at all
Cmakes all drugs effective orally
Dconcentrates the drug at the diseased site, reducing the dose needed and the side effects
Answer is hidden
Question 76 of 78Nanotechnology
Superparamagnetic iron oxide nanoparticles are used in medicine principally as
Aoral antibiotics
BX-ray shielding
Ccontrast agents for magnetic resonance imaging and for magnetic hyperthermia
Dstructural implants
Answer is hidden
Question 77 of 78Nanotechnology
Nano-fertilizers offer an advantage over conventional fertilizers because they
Aeliminate the need for soil
Bcontain no nutrients at all
Crelease nutrients in a controlled manner, so less is needed and runoff losses are reduced
Ddissolve instantly and completely on application
Answer is hidden
Question 78 of 78Nanotechnology
The toxicity of a nanomaterial depends on
Aits size, shape, surface chemistry and solubility, not on its chemical composition alone
Bnothing, since all nanomaterials are safe
Cits chemical composition alone
Dits colour
Answer is hidden