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This section covers synthetic fuels from biomass, thermochemical, physico-chemical and biochemical conversion, bio-fuel cells, basic electrochemistry, PEM and solid oxide fuel cells, and hydrogen production and storage.
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Biomass and Conversion Routes • Biomass is organic material of recent biological origin — wood, agricultural residue, energy crops, animal dung, and the organic fraction of municipal and industrial waste.
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It is considered carbon neutral in principle, because the carbon dioxide released on combustion was absorbed from the atmosphere during growth — but this holds only if the biomass is replaced by regrowth, so unsustainable harvesting is not carbon neutral at all.
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This qualification is examined directly. • The three conversion routes must be kept clearly apart, since questions turn on the distinction:
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Route Processes Products Conditions Thermochemical Direct combustion Heat Full air supply Gasification Producer gas or syngas (CO, H₂, CH₄) Sub-stoichiometric air, oxygen or steam at 800-1000 °C Pyrolysis Bio-oil, char and gas No oxygen at all, 400-600 °C Torrefaction Dry, brittle, energy-dense solid fuel Mild heating at 200-300 °C without oxygen Physico-chemical Extraction and transesterification Biodiesel and glycerine Vegetable oil or fat plus methanol with an alkali catalyst Briquetting and pelletising Densified solid fuel Mechanical compaction Biochemical Anaerobic digestion Biogas (50-70 % CH₄) and digestate Airtight digester, mesophilic 30-40 °C or thermophilic 50-60 °C Alcoholic fermentation Ethanol Yeast acting on sugars or hydrolysed starch Composting Compost and heat Aerobic • The distinction between combustion, gasification and pyrolysis is the one most often asked, and it turns entirely on the oxygen supply: combustion has a full supply, gasification a deliberately restricted one, and pyrolysis none at all. • Biogas is the most important bioenergy technology in Nepal.
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Anaerobic digestion proceeds in four stages — hydrolysis, acidogenesis, acetogenesis and methanogenesis — the last being the slowest and the most sensitive, since methanogens are strict anaerobes that require a pH near neutral, between about 6.8 and 7.2, and a stable temperature.
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Biogas contains 50-70 per cent methane with most of the balance carbon dioxide, and has a calorific value of about 20-25 MJ/m³. • The fixed-dome digester, of which the GGC 2047 model is the Nepali standard, has no moving parts and a long life, and the gas pressure varies as gas accumulates; the floating-drum type delivers gas at constant pressure but the steel drum corrodes.
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Nepal's domestic biogas programme has installed several hundred thousand plants and is among the most successful in the world; performance falls off at low temperature, which is why plants work well in the Terai and mid-hills but poorly at high altitude. • Its benefits should be listed: clean cooking gas replacing fuelwood, with the associated reduction in indoor air pollution and in time spent collecting wood; a high-quality digested slurry fertilizer; sanitary disposal where latrines are connected; and reduced deforestation. • Improved cooking stoves raise the efficiency of fuelwood use from roughly 10 per cent for a traditional three-stone fire to 20-25 per cent, and vent the smoke outside, which is the greater health benefit, since indoor air pollution from cooking is a major cause of respiratory disease among women and children. • Biofuel generations: first from food crops, second from lignocellulosic residues and wastes, third from algae — the progression driven by the food-versus-fuel objection and by land use concerns.
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Basic Electrochemistry and Fuel Cells • In both galvanic and electrolytic cells, oxidation occurs at the anode and reduction at the cathode.
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But the sign convention reverses: the anode is negative in a galvanic cell and positive in an electrolytic cell — a classic point of confusion and a standard question. • A galvanic cell converts chemical energy to electrical energy spontaneously; an electrolytic cell consumes electrical energy to drive a non-spontaneous reaction. • A fuel cell is a galvanic cell in which the reactants are supplied continuously from outside, so it does not run down as a battery does but generates as long as fuel is supplied.
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That continuous supply is what distinguishes a fuel cell from a battery, and it is examined directly. • The defining thermodynamic advantage, which should be stated in any answer: a fuel cell converts chemical energy directly into electrical energy without an intermediate conversion to heat and mechanical work, so it is not subject to the Carnot limitation.
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Practical electrical efficiencies of 40-60 per cent are achieved, rising to 85 per cent or more in combined heat and power. • The hydrogen-oxygen cell: at the anode, H₂ → 2H⁺ + 2e⁻; at the cathode, ½O₂ + 2H⁺ + 2e⁻ → H₂O; overall 2H₂ + O₂ → 2H₂O.
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The only by-product is water, which is the environmental attraction.
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Type Electrolyte Temperature Characteristics and use PEM (proton exchange membrane) Solid polymer membrane 60-100 °C Quick start, compact, high power density; requires pure hydrogen and a platinum catalyst that is poisoned by carbon monoxide; the type used in vehicles Alkaline (AFC) Potassium hydroxide solution 60-250 °C High efficiency but intolerant of carbon dioxide; used in spacecraft Phosphoric acid (PAFC) Phosphoric acid 150-220 °C Mature and tolerant of impurities; stationary CHP Molten carbonate (MCFC) Molten carbonate salt 600-700 °C Internal reforming of natural gas; no precious metal catalyst; stationary power Solid oxide (SOFC) Solid ceramic (yttria-stabilised zirconia) 600-1000 °C Highest efficiency, tolerant of carbon monoxide, can use natural gas directly; slow to start and subject to thermal stress; stationary generation • The PEM and SOFC comparison is the one examined:
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PEM operates at low temperature, starts quickly and suits vehicles but needs pure hydrogen and a platinum catalyst that carbon monoxide poisons;
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SOFC operates at high temperature, reaches the highest efficiency, tolerates carbon monoxide and can reform fuel internally, but takes hours to start and is subject to thermal stress, so it suits continuous stationary operation. • A microbial fuel cell (bio-fuel cell) uses micro-organisms to oxidise organic matter at the anode, transferring electrons to the electrode, so that wastewater treatment and electricity generation occur together.
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Its power density is at present very low, so it remains a research and niche technology, valued more as a self-powered sensor and as a route to energy-neutral wastewater treatment than as a power source.
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Hydrogen Production and Storage • Hydrogen is an energy carrier, not a source; it must be manufactured, and the energy content of the product is always less than the energy consumed in making it. • Production routes: steam methane reforming, which supplies the great majority of world production and is cheapest but releases carbon dioxide; partial oxidation and autothermal reforming; coal gasification; electrolysis of water, which gives very pure hydrogen and is clean if the electricity is renewable but is more expensive; and biological, thermochemical and photoelectrochemical routes, which remain developmental. • The colour convention is worth knowing: green hydrogen from electrolysis using renewable electricity; blue from fossil fuel with carbon capture; grey from fossil fuel without capture; and, in some usages, pink from nuclear electricity. • Electrolysis:
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2H₂O → 2H₂ + O₂, with hydrogen at the cathode and oxygen at the anode in a 2:1 volume ratio; the theoretical decomposition voltage is 1.23 V but practical cells need 1.8-2.0 V because of overpotentials and resistance, giving an efficiency of roughly 60-80 per cent. • Storage is the central difficulty, and the reason should be stated precisely: hydrogen has by far the highest energy content per unit mass of any fuel, about 120 MJ/kg against 44 for petrol, but a very low energy content per unit volume, because its density is so low.
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It is the volumetric energy density, not the gravimetric, that makes storage hard, and this is the point most often missed. • Methods: compressed gas at 350-700 bar, the commonest, but requiring heavy tanks; liquefaction at −253 °C, which is very energy intensive, consuming some 30 per cent of the energy stored, and suffers continuous boil-off; metal hydrides, which are safe and compact but heavy and slow; and chemical carriers such as ammonia, methanol and liquid organic hydrogen carriers. • Safety: hydrogen has very wide flammability limits, from about 4 to 75 per cent in air, a very low ignition energy, and a flame that is almost invisible in daylight; against this, it is extremely buoyant and disperses upward very rapidly in the open, so outdoor leaks are far less dangerous than an equivalent leak of a heavier fuel.
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Hydrogen embrittlement of steels is a further engineering constraint. • For Nepal, the attraction of hydrogen is as a means of using surplus monsoon hydropower that would otherwise be spilled, converting it to a storable and transportable form and reducing petroleum imports; green hydrogen and its use for fertilizer manufacture and transport have been the subject of study and of a national policy framework, but development is at an early stage.