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This section covers the objectives of water treatment and the removal of impurities through screening, plain sedimentation, sedimentation with coagulation, filtration, disinfection, softening and miscellaneous treatments, the principles of granular media filtration including slow sand, rapid gravity and roughing filters with backwashing and air scouring, sludge treatment, the calculation of effective size, uniformity coefficient and head loss, and advanced processes.
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The Treatment Train • The conventional sequence is: screening → aeration (where required) → coagulation → flocculation → sedimentation → filtration → disinfection → storage.
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Each unit prepares the water for the next, and the order cannot be altered — sedimentation before filtration, and filtration before disinfection, because turbidity shields organisms from the disinfectant. • Which impurity is removed where: screens remove floating and large suspended matter; aeration removes dissolved gases and oxidises iron and manganese; plain sedimentation removes settleable solids; coagulation and flocculation convert colloids into settleable flocs; sedimentation then removes them; filtration removes the remaining fine and colloidal matter and much of the bacteria; and disinfection destroys the pathogens that remain. • Aeration by cascade, spray, tray or diffused air serves to add oxygen, drive off carbon dioxide, hydrogen sulphide and volatile taste and odour compounds, and oxidise iron and manganese to insoluble forms that can then be settled and filtered.
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Screening and Sedimentation • Coarse screens (bar racks) with openings of 50-100 mm remove large debris; fine screens of 5-20 mm remove smaller material.
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Screens are cleaned manually or mechanically, and the approach velocity is kept around 0.6-1.0 m/s to prevent both deposition and excessive head loss. • Plain sedimentation removes discrete particles under gravity.
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The governing quantity is the surface overflow rate, SOR = Q/As, which has the units of velocity and equals the settling velocity of the smallest particle that is completely removed. • The fundamental and most examined result of ideal settling theory is that the removal of discrete particles depends only on the surface area of the tank and not on its depth, because a particle entering at the surface must settle the full depth in the time it takes to traverse the tank, and both depth terms cancel.
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Depth matters in practice for sludge storage, for avoiding scour and for hydraulic stability, but not for the theoretical efficiency.
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This conclusion is the basis of the tube and plate settler, which multiplies the effective settling area within the same tank volume. • Detention time t = V/Q, commonly 2-4 hours in a plain sedimentation tank and 1.5-3 hours after coagulation.
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Typical surface overflow rates are 15-30 m³/m²·d for plain sedimentation and 20-40 m³/m²·d with coagulation. • Zones of a settling tank: inlet, settling, sludge and outlet.
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The inlet must distribute the flow uniformly across the full section and dissipate its energy, and the outlet weir must draw off uniformly; short-circuiting caused by poor inlet or outlet arrangement, by density currents or by wind is the commonest reason a tank performs below its theoretical capacity. • Types: horizontal flow rectangular, radial flow circular, upflow clarifier, and the solids-contact clarifier, which combines mixing, flocculation and settling in one unit and uses a sludge blanket to improve floc formation.
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Coagulation and Flocculation • Colloidal particles of 1 nm to 1 μm carry a negative surface charge, so they repel one another and remain in suspension indefinitely — the settling time of a 1 μm clay particle is measured in years.
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Coagulation destabilises them and flocculation brings them together. • The distinction must be exact, because it is examined constantly: coagulation is the chemical destabilisation of the colloids by addition of a coagulant, accomplished in a rapid mix of 30-60 seconds at high velocity gradient; flocculation is the slow, gentle stirring for 20-40 minutes at low velocity gradient which brings the destabilised particles into contact so that they aggregate into settleable flocs.
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Mixing that is too vigorous during flocculation breaks the flocs up again, which is why the velocity gradient must be low and is often tapered, decreasing along the flocculator. • Mechanisms of coagulation: double layer compression, charge neutralisation, sweep coagulation by enmeshment in the precipitating hydroxide, and interparticle bridging by polymers. • Coagulants: alum, Al₂(SO₄)₃·18H₂O, is the commonest and cheapest and works best at pH 5.5-8.0; ferric chloride and ferric sulphate work over a wider pH range, 4-11, and give a denser floc; polyaluminium chloride requires a smaller dose and consumes less alkalinity; and lime and soda ash are used as coagulant aids as well as for softening. • Alum consumes alkalinity, so where the natural alkalinity is insufficient the pH falls and coagulation fails; lime or soda ash must then be added.
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This alkalinity requirement is a standard examination point. • Coagulant aids — polyelectrolytes, activated silica, bentonite clay and adjustment of pH — strengthen the floc, increase its density and reduce the coagulant dose. • The jar test is the standard laboratory method for determining the optimum coagulant dose and pH, since the optimum depends on the particular raw water and cannot be calculated theoretically — a point often asked.
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Filtration • Mechanisms of granular media filtration: straining at the surface, sedimentation within the pores, interception, adsorption and, in a slow sand filter, biological action.
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Straining alone accounts for only a small part of the removal in a rapid filter, where depth filtration within the bed dominates. • Effective size and uniformity coefficient — the two definitions that appear in every paper: • Effective size, D₁₀, is the sieve size in millimetres through which 10 per cent of the sand by weight passes. • Uniformity coefficient is D₆₀/D₁₀, the ratio of the size passing 60 per cent to the effective size.
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A uniformity coefficient of 1 would mean perfectly uniform sand, and the lower the value the more uniform the medium.
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Typical values are D₁₀ of 0.2-0.4 mm with a uniformity coefficient of 2-3 for slow sand filters, and D₁₀ of 0.4-0.7 mm with a uniformity coefficient of 1.3-1.7 for rapid gravity filters. • Head loss through a clean bed is given by the Carman-Kozeny or Rose equation, and it increases as the filter clogs; filtration is stopped and the filter cleaned when the head loss reaches the available head — typically 2-3 m in a rapid filter — or when the filtrate quality deteriorates, whichever occurs first. • Negative head develops when the head loss in the upper part of the bed exceeds the depth of water above it, so the pressure there falls below atmospheric; dissolved air comes out of solution and forms bubbles that blind the bed, a condition called air binding.
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Providing sufficient depth of water over the bed prevents it.
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Feature Slow sand filter Rapid gravity filter Filtration rate 0.1-0.2 m/h (2-5 m³/m²·d) 5-15 m/h (120-360 m³/m²·d) Effective size 0.2-0.4 mm 0.4-0.7 mm Feature Slow sand filter Rapid gravity filter Uniformity coefficient 2-3 1.3-1.7 Area required Large, about 50 times that of a rapid filter Small Pre-treatment No coagulation required; plain sedimentation only Coagulation and flocculation essential Cleaning Scraping off the top 20-25 mm of sand, every 1-3 months Backwashing, every 24-48 hours Removal mechanism Biological action in the schmutzdecke plus physical straining Predominantly physical, within the depth of the bed Bacterial removal Very high, 99-99.9 per cent Lower, 90-99 per cent; disinfection essential Operation Simple, little skill, no chemicals Skilled operation, chemicals, power for backwashing Suitability Low turbidity raw water, small communities, rural areas High and variable turbidity, urban supplies • The schmutzdecke, the biological layer that forms at the surface of a slow sand filter after a ripening period of a few days to weeks, is responsible for much of its purification, and this biological action is what a rapid filter lacks.
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When the filter is scraped, only the top 20-25 mm is removed and the schmutzdecke must re-form, so the filtrate is run to waste until it ripens again.
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Slow sand filtration is particularly well suited to Nepali rural schemes because it needs no chemicals, no power and little skill. • Backwashing reverses the flow at 0.4-1.0 m/min to expand the bed by 20-50 per cent, fluidising the grains so that the accumulated material is released and carried away, for 5-10 minutes.
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Air scouring, in which air is blown up through the bed before or with the water, greatly improves cleaning by breaking up mudballs and dislodging material that water alone cannot remove, and it reduces the quantity of wash water needed.
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Wash water use is typically 1-5 per cent of the filtered output, and excessive expansion is wasteful and can carry media out of the filter. • A roughing filter is a coarse-media filter, of gravel graded from coarse to fine in the direction of flow, placed before a slow sand filter to reduce a high turbidity that would otherwise clog it.
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It may be horizontal flow, upflow or downflow, and it acts principally by sedimentation within the pores rather than by straining.
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Roughing filtration with slow sand filtration — multi-stage filtration — is the standard arrangement for turbid hill streams in Nepal, and it avoids the need for chemical coagulation entirely. • Dual and multi-media filters place coarse light anthracite above fine heavy sand, so that the water meets coarse media first and the whole depth of the bed is used, giving a longer run and greater capacity than a single medium in which the finest grains end up on top after backwashing.
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Disinfection • Disinfection destroys pathogenic organisms; sterilisation destroys all organisms and is neither necessary nor practicable for a public supply. • Chlorine is the standard disinfectant because it is effective, cheap, easily applied and measured, and — uniquely among the common disinfectants — leaves a residual that protects the water throughout the distribution system.
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The residual is the decisive advantage and is examined directly. • Chemistry:
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Cl₂ + H₂O → HOCl + HCl, and HOCl ⇌ H⁺ + OCl⁻.
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Hypochlorous acid and hypochlorite ion together constitute the free available chlorine, and HOCl is some 80-100 times more effective than OCl⁻.
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Since the dissociation is governed by pH, with HOCl dominant below pH 7.5 and OCl⁻ above it, chlorination is far more effective in slightly acidic water and much less so in alkaline water.
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This pH dependence is the most examined fact about chlorination. • Combined chlorine (chloramines) forms when chlorine reacts with ammonia; it is a weaker and slower disinfectant but far more persistent, so it is used to maintain a residual in a long distribution system. • Breakpoint chlorination: as chlorine is added, it is first consumed by reducing agents, then forms chloramines whose concentration rises, then destroys those chloramines so that the measured residual falls to a minimum — the breakpoint — beyond which further addition appears entirely as free residual chlorine.
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Dosing beyond the breakpoint is necessary to obtain a free residual. • Factors affecting efficiency: contact time, concentration, pH, temperature, turbidity and the nature of the organism.
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The product of concentration and contact time, the CT value, is the measure used in practice.
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Turbidity must be removed first, because particles shield organisms from the disinfectant — which is why filtration always precedes disinfection. • A residual of 0.2-0.5 mg/L free chlorine is normally maintained at the far end of the distribution system, with a contact time of at least 30 minutes. • Disinfection by-products: chlorine reacts with natural organic matter to form trihalomethanes and haloacetic acids, some of which are suspected carcinogens.
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They are minimised by removing the organic precursors before chlorination rather than by reducing the disinfection, since the risk from inadequate disinfection is immediate and far greater than the long-term risk from by-products — a judgement worth stating explicitly. • Alternatives: ozone, the most powerful, which also removes taste, odour and colour but leaves no residual and is costly; ultraviolet radiation, which is effective against bacteria, viruses and, importantly, the chlorine-resistant protozoa Cryptosporidium and Giardia, but also leaves no residual and requires clear water; and, at household level, boiling, solar disinfection (SODIS), chlorine tablets and ceramic or biosand filters.
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That ozone and UV leave no residual is their common and decisive limitation for a piped system.
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Softening, Sludge and Advanced Processes • Hardness is caused by calcium and magnesium ions and is expressed as mg/L of CaCO₃.
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Carbonate (temporary) hardness is associated with bicarbonate and is removed by boiling or by lime; non-carbonate (permanent) hardness is associated with sulphate and chloride and requires soda ash or ion exchange.
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Water of under 75 mg/L is soft and over 300 mg/L very hard.
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Hard water wastes soap, forms scale in boilers and pipes, and spoils cooking; very soft water is corrosive. • Softening methods: the lime-soda process, in which lime removes carbonate hardness and soda ash non-carbonate hardness, with excess lime used where magnesium must be removed; the zeolite or ion exchange process, which exchanges calcium and magnesium for sodium and can reduce hardness to almost zero but adds sodium and cannot handle turbid water; and membrane processes.
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Blending softened with unsoftened water is usual, since water of zero hardness is corrosive. • Sludge treatment: alum sludge from the clarifiers is thickened by gravity, conditioned, dewatered on drying beds, by centrifuge or filter press, and then disposed of by landfill or land application; lagoons are used in small plants.
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Alum sludge is gelatinous and very difficult to dewater, which is the principal practical difficulty.
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Discharging clarifier and backwash sludge directly to a watercourse is unacceptable and is a common failing of small plants. • Advanced processes: • Activated carbon — powdered activated carbon dosed before sedimentation for intermittent taste and odour problems, or granular activated carbon in a bed for continuous removal of organic compounds, taste, odour and colour by adsorption. • Ion exchange — used for softening, demineralisation, nitrate removal and arsenic removal, with the resin regenerated by brine or acid and alkali; the spent regenerant is a concentrated waste needing disposal. • Membrane processes, whose order must be known: microfiltration removes suspended solids, protozoa and most bacteria; ultrafiltration adds viruses and macromolecules; nanofiltration removes divalent ions and is therefore used for softening; and reverse osmosis removes monovalent ions, giving desalination.
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The required pressure and the cost rise in that order, and reverse osmosis requires the highest pressure because it must overcome the osmotic pressure of the solution.
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All membrane processes suffer from fouling and require pre-treatment, and all produce a concentrate that must be disposed of. • Iron and manganese removal by aeration followed by sedimentation and filtration, or by contact filtration with an oxidising medium.
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Arsenic removal by oxidation to the pentavalent form followed by coagulation with iron salts, adsorption on activated alumina or iron-based media, or membrane treatment; the trivalent form must be oxidised first, because it is far less readily removed.
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Fluoride removal by activated alumina, bone char or the Nalgonda technique using alum and lime.
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Defluoridation and arsenic removal are both of direct relevance in parts of Nepal.