AChE/Chapter 4/Read MCQs
📖 Back to Study Notes
4

Chapter 4 · MCQ Read Mode

Chemical Reaction Engineering

ACHE04·78 Total MCQs
Question 1 of 78Mole Balances

The design equation for an ideal CSTR is

AV = FA0X/(−rA) with the rate evaluated at inlet conditions
BV = FA0X/(−rA) with the rate evaluated at exit conditions
CV = FA0∫dX/(−rA)
DV = NA0∫dX/(−rAV)
Answer is hidden
Question 2 of 78Mole Balances

For a reaction of positive order, the volume of a PFR compared with that of a CSTR achieving the same conversion is

Asmaller, and the difference increases with conversion
Bsmaller only at very low conversion
Clarger, and the difference increases with conversion
Dexactly equal at all conversions
Answer is hidden
Question 3 of 78Mole Balances

A CSTR is preferred over a PFR at low conversion for

Aa second-order irreversible reaction
Ba first-order irreversible reaction
Can autocatalytic reaction
Da zero-order reaction
Answer is hidden
Question 4 of 78Mole Balances

Space time is defined as

Athe time taken for the reaction to reach equilibrium
Breactor volume multiplied by the inlet volumetric flow rate
Cthe reciprocal of the reaction rate constant
Dreactor volume divided by the volumetric flow rate at the inlet
Answer is hidden
Question 5 of 78Mole Balances

Space time equals the mean residence time only when

Athe reactor is a CSTR
Bthe reaction is first order
Cthe volumetric flow rate is constant throughout the reactor
Dthe conversion is complete
Answer is hidden
Question 6 of 78Mole Balances

For a gas-phase reaction A gives 2B carried out at constant temperature and pressure with pure A fed, the value of epsilon is

A−0.5
B2
C1
D0
Answer is hidden
Question 7 of 78Mole Balances

For N equal-sized CSTRs in series carrying out a first-order reaction, the exit concentration ratio is

A1/(1 + Nkτi)
Bexp(−Nkτi)
C1/(1 + kτi)N
D(1 + kτi)N
Answer is hidden
Question 8 of 78Mole Balances

As the number of equal CSTRs in series is increased at a fixed total volume, the conversion

Aincreases and approaches that of a PFR of the same total volume
Bdecreases steadily
Cfirst increases and then decreases
Dremains unchanged
Answer is hidden
Question 9 of 78Mole Balances

In a series of reactors, the conversion used in the design equation for the second reactor is measured

Aas the average of inlet and outlet
Bfrom the feed to the second reactor only
Cfrom the feed to the first reactor
Das zero at the inlet of each reactor
Answer is hidden
Question 10 of 78Mole Balances

The rate of reaction for a fluid-solid catalytic reaction is most commonly expressed per unit

Amole of feed
Bvolume of fluid
Cvolume of reactor
Dmass of catalyst
Answer is hidden
Question 11 of 78Mole Balances

A plug flow reactor is conceptually equivalent to

Atwo CSTRs in parallel
Ban infinite number of infinitesimally small CSTRs in series
Ca batch reactor operated at steady state
Da single very large CSTR
Answer is hidden
Question 12 of 78Mole Balances

A fluidized bed reactor is preferred over a fixed bed reactor mainly when

Aplug flow behaviour is required
Ba very narrow residence time distribution is essential
Cattrition of the catalyst must be avoided
Dthe catalyst deactivates rapidly and requires continuous regeneration
Answer is hidden
Question 13 of 78Mole Balances

For a batch reactor operating at constant volume, the design equation reduces to

At = CA0X/(−rA)
Bt = CA0∫dX/(−rA)
Ct = V/v0
Dt = FA0∫dX/(−rA)
Answer is hidden
Question 14 of 78Rate Laws, Stoichiometry and Isothermal Reactor Design

The order of a reaction

Ais always a positive integer
Bmust be determined experimentally and may be fractional or negative
Cis always equal to the sum of the stoichiometric coefficients
Dequals the molecularity in every case
Answer is hidden
Question 15 of 78Rate Laws, Stoichiometry and Isothermal Reactor Design

For which reaction order is the half-life independent of the initial concentration?

AFirst order
BThird order
CSecond order
DZero order
Answer is hidden
Question 16 of 78Rate Laws, Stoichiometry and Isothermal Reactor Design

A plot of 1/Cₐ against time gives a straight line. The reaction is

Asecond order
Bzero order
Cfirst order
Dhalf order
Answer is hidden
Question 17 of 78Rate Laws, Stoichiometry and Isothermal Reactor Design

The rate constant of a reaction has units of s^-1. The reaction is

Azero order
Bsecond order
Cfirst order
Dthird order
Answer is hidden
Question 18 of 78Rate Laws, Stoichiometry and Isothermal Reactor Design

In the Arrhenius equation, a plot of ln k against 1/T gives a straight line whose slope equals

A−Ea
B−Ea/R
CEa/R
D−R/Ea
Answer is hidden
Question 19 of 78Rate Laws, Stoichiometry and Isothermal Reactor Design

A reaction with a high activation energy is

Anecessarily zero order
Bstrongly sensitive to temperature changes
Cinsensitive to temperature changes
Dalways very fast at room temperature
Answer is hidden
Question 20 of 78Rate Laws, Stoichiometry and Isothermal Reactor Design

For a gas-phase reaction with epsilon greater than zero carried out at constant temperature and pressure, the concentration of reactant A

Afalls less steeply than in a constant-volume system
Bfalls more steeply with conversion than in a constant-volume system
Cis unaffected by the expansion
Dincreases with conversion
Answer is hidden
Question 21 of 78Rate Laws, Stoichiometry and Isothermal Reactor Design

For a first-order liquid-phase reaction in a CSTR, the conversion is given by

Akτ/(1 + kτ)
B1 − exp(−kτ)
Cexp(−kτ)
Dkτ
Answer is hidden
Question 22 of 78Rate Laws, Stoichiometry and Isothermal Reactor Design

If the space time of a first-order PFR is doubled, the conversion

Aincreases but by less than a factor of two
Bexactly doubles
Cremains unchanged
Dmore than doubles
Answer is hidden
Question 23 of 78Rate Laws, Stoichiometry and Isothermal Reactor Design

The correct order of steps in the isothermal reactor design algorithm is

Astoichiometry, combine, mole balance, rate law
Bmole balance, rate law, stoichiometry, combine, evaluate
Crate law, mole balance, evaluate, stoichiometry
Dcombine, evaluate, mole balance, rate law
Answer is hidden
Question 24 of 78Rate Laws, Stoichiometry and Isothermal Reactor Design

Pressure drop in a reactor is an important design consideration for

Agas-phase reactions in packed beds
Ball liquid-phase reactions
Creactions with epsilon equal to zero only
Dbatch reactors of any kind
Answer is hidden
Question 25 of 78Rate Laws, Stoichiometry and Isothermal Reactor Design

Increasing the catalyst particle size in a packed bed reactor will

Ahave no effect on either
Breduce the pressure drop but may lower the effectiveness factor
Cincrease the pressure drop and the effectiveness factor
Dreduce both the pressure drop and internal diffusion resistance
Answer is hidden
Question 26 of 78Rate Laws, Stoichiometry and Isothermal Reactor Design

A catalyst increases the rate of a reaction by

Aincreasing the activation energy of the reverse reaction only
Bincreasing the enthalpy of reaction
Clowering the activation energy of both the forward and reverse reactions equally
Draising the equilibrium constant
Answer is hidden
Question 27 of 78Collection and Analysis of Rate Data

In the integral method of analysing rate data, one

Adifferentiates the concentration data to obtain rates
Bmeasures only the initial rate at several concentrations
Cassumes a reaction order, integrates the rate law and tests the data for linearity
Dmeasures the half-life at a single concentration
Answer is hidden
Question 28 of 78Collection and Analysis of Rate Data

The differential method of rate-data analysis determines the reaction order from

Athe slope of a plot of ln k against 1/T
Bthe value of the half-life alone
Cthe intercept of a plot of CA against t
Dthe slope of a plot of ln(−rA) against ln CA
Answer is hidden
Question 29 of 78Collection and Analysis of Rate Data

The main disadvantage of the differential method compared with the integral method is that it

Aneeds data at several temperatures
Bamplifies experimental scatter through the differentiation step
Crequires the reaction to be first order
Dcannot handle fractional orders
Answer is hidden
Question 30 of 78Collection and Analysis of Rate Data

When reactant B is present in very large excess, the observed kinetics are described as

Azero order in A
Bpseudo-order, with a pseudo-rate constant absorbing the constant concentration of B
Cindependent of the concentration of A
Dtrue second order
Answer is hidden
Question 31 of 78Collection and Analysis of Rate Data

In a differential reactor, the conversion across the catalyst bed is deliberately kept

Avery small, so the rate can be treated as constant throughout the bed
Bat the equilibrium value
Cvery large, to maximise the measured signal
Dexactly 50 per cent
Answer is hidden
Question 32 of 78Collection and Analysis of Rate Data

Which laboratory reactor allows the reaction rate to be obtained directly at steady state without any integration?

AA batch reactor
BAn integral packed-bed reactor
CA plug flow reactor
DA well-mixed recycle or Berty CSTR
Answer is hidden
Question 33 of 78Collection and Analysis of Rate Data

Selectivity in a multiple-reaction system is defined as

Athe ratio of reactor volume to feed rate
Bthe fraction of reactant converted
Cthe ratio of desired product formed to reactant consumed
Dthe ratio of the desired product formed to the undesired product formed
Answer is hidden
Question 34 of 78Collection and Analysis of Rate Data

For the parallel reactions A to D (desired, second order in A) and A to U (undesired, first order in A), the desired product is favoured by

Aoperating at very high conversion
Bmaintaining a low concentration of A in a CSTR
Cadding a large quantity of inert diluent
Dmaintaining a high concentration of A, for example in a PFR or batch reactor
Answer is hidden
Question 35 of 78Collection and Analysis of Rate Data

A semi-batch reactor in which one reactant is added slowly to the other is particularly useful for

Aachieving perfect plug flow
Breaching equilibrium more rapidly
Ckeeping one reactant concentration low and the other high to improve selectivity
Deliminating all temperature gradients
Answer is hidden
Question 36 of 78Collection and Analysis of Rate Data

If the desired reaction has a higher activation energy than the undesired reaction, selectivity is improved by operating at

Athe equilibrium temperature
Ba temperature that has no effect on selectivity
Ca low temperature
Da high temperature
Answer is hidden
Question 37 of 78Collection and Analysis of Rate Data

For the series reaction A to B to C with first-order steps, the concentration of B

Aincreases monotonically with time
Bremains constant throughout
Cdecreases monotonically from the start
Dpasses through a maximum at a definite optimum time
Answer is hidden
Question 38 of 78Collection and Analysis of Rate Data

For maximising the yield of the intermediate B in the series reaction A to B to C

Athe reactor type is irrelevant
Ba PFR gives a higher maximum yield than a CSTR
Cboth give identical maximum yields
Da CSTR gives a higher maximum yield than a PFR
Answer is hidden
Question 39 of 78Collection and Analysis of Rate Data

When several reactions occur simultaneously, the mole balances are most conveniently written in terms of

Athe overall yield alone
Bthe total pressure only
Cthe molar flow rate or concentration of each species
Dthe conversion of the limiting reactant only
Answer is hidden
Question 40 of 78Reaction Mechanisms, Enzyme Kinetics and Non-isothermal Reactors

The pseudo-steady-state hypothesis assumes that

Athe total pressure remains constant
Bthe net rate of formation of each active intermediate is zero
Call reactions are elementary
Dthe reaction rate is independent of temperature
Answer is hidden
Question 41 of 78Reaction Mechanisms, Enzyme Kinetics and Non-isothermal Reactors

In the Michaelis-Menten equation, the constant Kₘ represents

Athe maximum reaction rate
Bthe total enzyme concentration
Cthe substrate concentration at which the rate is half of Vmax
Dthe equilibrium constant of the overall reaction
Answer is hidden
Question 42 of 78Reaction Mechanisms, Enzyme Kinetics and Non-isothermal Reactors

At substrate concentrations far above Kₘ, an enzyme-catalysed reaction is

Azero order in substrate
Bof fractional order
Csecond order in substrate
Dfirst order in substrate
Answer is hidden
Question 43 of 78Reaction Mechanisms, Enzyme Kinetics and Non-isothermal Reactors

A Lineweaver-Burk plot is a plot of

A1/rate against 1/substrate concentration
Brate against substrate concentration
Cln rate against ln substrate concentration
Drate against 1/temperature
Answer is hidden
Question 44 of 78Reaction Mechanisms, Enzyme Kinetics and Non-isothermal Reactors

Competitive inhibition of an enzyme is characterised by

Aa decreased Vmax with KM unchanged
Ban increased apparent KM with Vmax unchanged
Cno change in either parameter
Da decrease in both Vmax and KM
Answer is hidden
Question 45 of 78Reaction Mechanisms, Enzyme Kinetics and Non-isothermal Reactors

In a chemostat operating at steady state, the specific growth rate of the cells equals

Athe dilution rate
Bthe maximum specific growth rate
Cthe substrate consumption rate
Dzero
Answer is hidden
Question 46 of 78Reaction Mechanisms, Enzyme Kinetics and Non-isothermal Reactors

Washout occurs in a chemostat when

Athe temperature falls below the optimum
Bthe dilution rate exceeds the maximum specific growth rate
Cthe dilution rate is reduced to zero
Dthe substrate concentration is too high
Answer is hidden
Question 47 of 78Reaction Mechanisms, Enzyme Kinetics and Non-isothermal Reactors

For an adiabatic reactor, the relation between temperature and conversion is

Alogarithmic
Bindependent of conversion
Cexponential
Dlinear
Answer is hidden
Question 48 of 78Reaction Mechanisms, Enzyme Kinetics and Non-isothermal Reactors

For an exothermic reversible reaction, the equilibrium conversion

Ais independent of temperature
Bincreases as the temperature increases
Cdecreases as the temperature increases
Dincreases with pressure only
Answer is hidden
Question 49 of 78Reaction Mechanisms, Enzyme Kinetics and Non-isothermal Reactors

Interstage cooling between catalyst beds in an exothermic reversible reaction is used to

Areduce the pressure drop through the system
Bprevent the catalyst from being reduced
Crestore a favourable equilibrium by lowering the temperature before the next bed
Dincrease the reaction rate in the bed just completed
Answer is hidden
Question 50 of 78Reaction Mechanisms, Enzyme Kinetics and Non-isothermal Reactors

When the heat generation curve and heat removal line for a CSTR intersect at three points, the middle steady state is

Astable
Bthe point of maximum conversion
Cthe most efficient operating point
Dunstable
Answer is hidden
Question 51 of 78Reaction Mechanisms, Enzyme Kinetics and Non-isothermal Reactors

Parametric sensitivity in an exothermic packed-bed reactor means that temperature

Athe conversion is independent of the catalyst weight
Ba very small change in an operating variable produces a disproportionately large change in the peak
Cthe reaction rate is insensitive to temperature
Dthe pressure drop controls the conversion
Answer is hidden
Question 52 of 78Reaction Mechanisms, Enzyme Kinetics and Non-isothermal Reactors

The step in a chain reaction in which a radical reacts to give a product molecule and another radical is called

Atermination
Binhibition
Cpropagation
Dinitiation
Answer is hidden
Question 53 of 78Catalysis, Diffusion Effects and Residence Time Distribution

The correct sequence of steps in a heterogeneous catalytic reaction begins with

Asurface reaction
Bexternal diffusion of reactant from the bulk fluid to the catalyst surface
Cdesorption of product
Dadsorption of reactant on the active site
Answer is hidden
Question 54 of 78Catalysis, Diffusion Effects and Residence Time Distribution

Chemisorption differs from physisorption in that it

Aoccurs only at very low temperatures
Binvolves chemical bond formation, is monolayer and highly specific
Cis multilayer and non-specific
Dhas a very low heat of adsorption
Answer is hidden
Question 55 of 78Catalysis, Diffusion Effects and Residence Time Distribution

The BET method is used to determine

Athe effectiveness factor of a pellet
Bthe total surface area of a porous catalyst
Cthe activation energy of a reaction
Dthe residence time distribution
Answer is hidden
Question 56 of 78Catalysis, Diffusion Effects and Residence Time Distribution

In a Langmuir-Hinshelwood mechanism

Aneither reactant is adsorbed
Bthe reaction occurs entirely in the gas phase
Cone reactant reacts directly from the gas phase with an adsorbed species
Dboth reactants are adsorbed on the surface before reacting
Answer is hidden
Question 57 of 78Catalysis, Diffusion Effects and Residence Time Distribution

If a reaction product appears in the denominator of a heterogeneous catalytic rate law, it indicates that the product

Ais adsorbed on the catalyst and inhibits the reaction
Bis formed in the gas phase only
Caccelerates the reaction
Ddecomposes on the catalyst surface
Answer is hidden
Question 58 of 78Catalysis, Diffusion Effects and Residence Time Distribution

Which observation indicates that a catalytic reaction is controlled by external mass transfer?

AThe apparent activation energy is very high
BThe rate increases markedly when the fluid velocity past the particle is increased
CThe rate is proportional to the square of the concentration
DThe rate is unaffected by fluid velocity
Answer is hidden
Question 59 of 78Catalysis, Diffusion Effects and Residence Time Distribution

For a catalyst pellet with a very large Thiele modulus, the effectiveness factor is approximately

Aφ²
B1.0
C1/φ
Dφ
Answer is hidden
Question 60 of 78Catalysis, Diffusion Effects and Residence Time Distribution

When a reaction is strongly limited by internal pore diffusion, the apparent activation energy is approximately

Ahalf the true activation energy
Btwice the true activation energy
Cequal to the true activation energy
Dzero
Answer is hidden
Question 61 of 78Catalysis, Diffusion Effects and Residence Time Distribution

Loss of catalyst activity by the growth of metal crystallites at high temperature is called

Acoking
Bpoisoning
Csintering
Dfouling
Answer is hidden
Question 62 of 78Catalysis, Diffusion Effects and Residence Time Distribution

In a pulse tracer experiment, the normalised concentration response directly gives

Athe exit age distribution E(t)
Bthe reaction rate constant
Cthe cumulative distribution F(t)
Dthe effectiveness factor
Answer is hidden
Question 63 of 78Catalysis, Diffusion Effects and Residence Time Distribution

The variance of the residence time distribution for an ideal plug flow reactor is

Ainfinite
Bzero
Cequal to τ
Dequal to τ²
Answer is hidden
Question 64 of 78Catalysis, Diffusion Effects and Residence Time Distribution

In the tanks-in-series model, the number of equivalent tanks is calculated as

AN = σ²/τ²
BN = σ/τ
CN = τ²/σ²
DN = τ/σ
Answer is hidden
Question 65 of 78Catalysis, Diffusion Effects and Residence Time Distribution

The residence time distribution alone is sufficient to predict conversion for

Afirst-order reactions
Bzero-order reactions
Call reactions regardless of order
Dsecond-order reactions
Answer is hidden
Question 66 of 78Biochemical Engineering

Which of the following is a prokaryotic organism?

ABacteria
BYeast
CFilamentous fungi
DAlgae
Answer is hidden
Question 67 of 78Biochemical Engineering

Sucrose on hydrolysis yields

Aglucose and galactose
Btwo molecules of glucose
Cfructose and galactose
Dglucose and fructose
Answer is hidden
Question 68 of 78Biochemical Engineering

Starch and cellulose are both polymers of glucose but differ in

Athe presence of nitrogen in cellulose
Btheir molecular weight alone
Cthe type of glycosidic linkage, alpha in starch and beta in cellulose
Dthe monomer, which is fructose in cellulose
Answer is hidden
Question 69 of 78Biochemical Engineering

The structural component of all cell membranes, being amphipathic, is

Aphospholipid
Bcellulose
Ctriglyceride
Dglycogen
Answer is hidden
Question 70 of 78Biochemical Engineering

Amino acids are joined together in a protein by

Apeptide bonds formed with the elimination of water
Bphosphodiester bonds
Cglycosidic bonds
Dhydrogen bonds only
Answer is hidden
Question 71 of 78Biochemical Engineering

The secondary structure of a protein, such as the alpha helix, is stabilised mainly by

Apeptide bonds
Bhydrogen bonds
Cdisulphide bridges only
Dionic bonds only
Answer is hidden
Question 72 of 78Biochemical Engineering

Which base is present in RNA but not in DNA?

AGuanine
BUracil
CCytosine
DThymine
Answer is hidden
Question 73 of 78Biochemical Engineering

In DNA, guanine pairs with cytosine through

Athree hydrogen bonds
Btwo hydrogen bonds
Can ionic bond
Da covalent bond
Answer is hidden
Question 74 of 78Biochemical Engineering

The net ATP yield from the complete aerobic oxidation of one molecule of glucose is approximately

A30 to 32
B2
C100
D4
Answer is hidden
Question 75 of 78Biochemical Engineering

The theoretical yield of ethanol from glucose by fermentation is about

A100 per cent by mass
B75 per cent by mass
C51 per cent by mass
D25 per cent by mass
Answer is hidden
Question 76 of 78Biochemical Engineering

The Pasteur effect refers to

Ainhibition of growth by the product
Bthe suppression of fermentation by the presence of oxygen
Cfermentation occurring despite the presence of oxygen
Ddenaturation of enzymes at high temperature
Answer is hidden
Question 77 of 78Biochemical Engineering

The lac operon of E. coli is an example of

Aa repressible system, normally switched on
Ba system unaffected by the presence of lactose
Ca eukaryotic regulatory system
Dan inducible system, normally switched off and turned on by its substrate
Answer is hidden
Question 78 of 78Biochemical Engineering

Immobilisation of an enzyme on a solid support typically results in

Acomplete loss of catalytic activity
Ba decreased apparent KM and no diffusional effects
Cconversion of the enzyme into a non-specific catalyst
Deasier reuse and separation but an increased apparent KM because of diffusion resistance
Answer is hidden
← PREVIOUS CHAPTERCh 3: Fluid Mechanics and Mechanical operationsNEXT CHAPTER →Ch 5: Energy and Heat Transfer